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science:gas

gas behaviour and equations

Introduction

  • most substances become gases once they have become liquids (at their melting point temperature) and then the temperature exceeds their boiling point temperature
  • NB. some substances sublime straight from solid to gas

Boiling point

  • this is the temperature at which a liquid will form gas bubbles and start to evaporate into its gaseous form
  • the vapour pressure of a liquid rises as its temperature increases
  • the boiling point temperature is when the liquid's vapour pressure exceeds that of the pressure of the space above it
  • the standard boiling point is measured when the space above it is normal atmospheric pressure of 1 atm
  • if the pressure of the space above it falls then the boiling point temperature falls (eg. high altitude)
    • this is why butane gas stoves can work in freezing conditions at high altitude but not at normal altitudes
  • if the pressure of the space above it increases, then the boiling point temperature increases (eg. pressure cooker, LPG bottles)

The Gas Equation

PV = nRT

  • where:
    • P = pressure in Pascal (N/m2)
    • V = volume of space the gas is contained within measured in m3
    • n = number of moles of gas substance in mol
    • R = the gas constant = 8.314 J/(mol.K)
    • T = temperature in degrees Kelvin K= Celsius temp + 273.15
  • NB. if use P in atm, V in litres, then the gas constant is 0.08206 L.atm/(mol.K)

moving gas from one volume space to another volume space

  • the PV product above remains constant as you have not lost any gas, hence:
    • P2V2 = P1V1
    • ie. the new pressure = P1V1 / V2

Gaseous pressure units

  • 1 atmosphere (atm) is the standard pressure of earth's atmosphere which equates to:
    • 1.01325 bar
    • 101.325 kPa
    • 760mmHg = 760 Torr
    • 14.696 pounds per square inch (psi)
science/gas.txt · Last modified: 2026/08/31 22:59 by gary1

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