science:gas
Table of Contents
gas behaviour and equations
Introduction
- most substances become gases once they have become liquids (at their melting point temperature) and then the temperature exceeds their boiling point temperature
- NB. some substances sublime straight from solid to gas
Boiling point
- this is the temperature at which a liquid will form gas bubbles and start to evaporate into its gaseous form
- the vapour pressure of a liquid rises as its temperature increases
- the boiling point temperature is when the liquid's vapour pressure exceeds that of the pressure of the space above it
- the standard boiling point is measured when the space above it is normal atmospheric pressure of 1 atm
- if the pressure of the space above it falls then the boiling point temperature falls (eg. high altitude)
- this is why butane gas stoves can work in freezing conditions at high altitude but not at normal altitudes
- if the pressure of the space above it increases, then the boiling point temperature increases (eg. pressure cooker, LPG bottles)
- vapour pressure of propane is much higher than that of butane and thus propane containers need to be build much stronger
- see comparison of gas options for hiking or camping for more details
The Gas Equation
PV = nRT
- where:
- P = pressure in Pascal (N/m2)
- V = volume of space the gas is contained within measured in m3
- n = number of moles of gas substance in mol
- R = the gas constant = 8.314 J/(mol.K)
- T = temperature in degrees Kelvin K= Celsius temp + 273.15
- NB. if use P in atm, V in litres, then the gas constant is 0.08206 L.atm/(mol.K)
moving gas from one volume space to another volume space
- the PV product above remains constant as you have not lost any gas, hence:
- P2V2 = P1V1
- ie. the new pressure = P1V1 / V2
Gaseous pressure units
- 1 atmosphere (atm) is the standard pressure of earth's atmosphere which equates to:
- 1.01325 bar
- 101.325 kPa
- 760mmHg = 760 Torr
- 14.696 pounds per square inch (psi)
science/gas.txt · Last modified: 2026/08/31 22:59 by gary1