when air temperature drops below its dewpoint temperature, water will begin to form dew or condensation on the colder surfaces where there is a colder boundary layer of that air and if this temperature falls below zero degC then it becomes frost (water condensation in air cooled to its dew point becomes fog or cloud and is called hydrometeors instead of dew).
dew or internal condensation can occur when high humidity air arises from:
the moist atmosphere (this type is called dewfall)
the wet soil beneath (in which case dew is said to form by distillation)
exhaled breathes increasing humidity within the inner tent
this can be reduced by:
venting the humid air out via mesh plus some wind
“breathable fabrics” which allow the water moisture to escape through the fabric
avoiding other sources of moisture such as wet gear, boiling water
warming the inner tent's inner surface
wet camping gear
dew is particularly problematic when the temperature falls with clear skies and minimal wind:
clear skies increase radiative cooling
lack of wind reduces flow of higher warm air downwards so the surface area gets cooler from ground cooling from radiative cooling, and also reduces disruptions to air boundary layers on surfaces
on natural surfaces, dew always occurs as dropwise condensation, following different stages from the heterogeneous nucleation of a single droplet, its growth by incorporation of water vapor molecules and its interactions with neighboring droplets by coalescences
if the wind speed is sufficient to disrupt the otherwise fairly stagnant boundary layer of air next to an object such as a tent wall, then the air layer next to the object will not be as cold and thus there will be less dew forming (this is evident on cars left out overnight - the wind side tends not to have dew or frost)
the temperature of the boundary layer of air (lining the surface of the object) is dependent upon:
ambient air temperature
temperature of the object surface compared to ambient air temperature
how slow the boundary air layer moves - natural + forced convection determinants
heat transfer coefficient of object - how quickly heat is transferred from the boundary layer of air to the colder object
the rate at which the surface of an object cools down overnight is dependent upon various factors:
cooling of the outer exposed surface is dependent upon:
prior cooling by cold air
radiative cooling of the outer surface occurs overnight due to a deficit between the emitted radiation from the surface and the radiation coming from the atmosphere
this cooling increases on nights with clear skies
surface emissivity
ie. its effectiveness in emitting energy as thermal radiation
the surface of a perfect black body (with an emissivity of 1) emits thermal radiation at the rate of approximately 448 watts per square metre (W/m2) at a room temperature of 25 °C (298 K; 77 °F).
examples with high surface emissivity and thus high risk of dew include glass, painted surfaces, poorly conducting objects, wood, most fabrics
most metals have low surface emissivity and thus lower risk of dew
the heat exchange coefficient with the surrounding air
convective cooling:
heat energy transferred between a surface and a moving fluid(air) with different temperatures - is known as convection
air may move either by:
rate of convective heat loss to air = heat transfer coefficient of object x surface area x (temp differential between bulk air and the surface of the object)
near the surface the air velocity is low, and diffusion dominates
at a distance from the surface, bulk motion increases the influence and dominates
high thermal resistance to heat conduction (this allows the temperature change to be more confined to the outer surface than transferred through to the inner surface)
thus outer surface radiative cooling is especially a factor with complex 3D geometries such as plant leaves, cactus spines, insect shells, spider nets, and poor conducting objects or well isolated from the ground, and non-metallic.
cooling of the inner surface is limited by the thermal resistance of the object (the ratio of its thickness to its surface area and thermal conductivity).
the dewpoint is a measure of the amount of water content in an air mass and its measurement is mainly determined by the temperature of the air mass and it's relative humidity (RH) - the greater the RH, the closer the dewpoint comes to the dry bulb temperature.
exhaled air contains 0.034g water per litre air (at 37degC, 1 liter of air is full saturated at 0.0436g water content) and generally has a temperature in the range of 31.4-35.4 °C and a RH of 40-100% (not always 100% as many state)1) and this results in some 100-150mL of water being exhaled into the tent overnight per person.
at 33degC and at 80% RH, the dewpoint will be approx. 29degC so it is easy to see that this is a major risk for condensation as most nights have air temperatures well below 29degC
if this exhaled water is not vented outside (eg. a fully sealed fabric inner canopy of a tent), the RH of the tent will increase quickly and the dewpoint will approach the tent temperature which will generally be much warmer than the outside air temperature. This will inevitably result in condensation on the inside of the tent fabric as this will be cooler from the outside air.